ELECTROMETALLURGY |
Metals manufacturing makes up a significant component of Canada's
economy. Through methods based on metal electrodeposition reactions,
Canada makes more than $5 billion worth of electrolytically produced
metals a year. Metal electrodeposition is also used in electroplating
in electronic devices and automotive parts, in ornamentation and
in finishing many commercial goods. Although technologies used
in electrolytic metals production and in electroplating are quite
mature, many methods were developed by trial and error, and their
scientific basis is poorly understood.
New tools for "in situ" studies of the morphology, surface
composition and crystallography of electrodeposited metals have
resulted from spectacular advances in surface imaging techniques,
such as atomic force microscopy (AFM), and in synchrotron-based
X-ray absorption spectroscopies, including X-ray absorption near
edge spectroscopy (XANES) and extended X-ray absorption fine structure
spectroscopy (EXAFS). In collaboration with INCO Ltd. and the
Centre for Chemical Process Metallurgy, University of Guelph researchers
simulate industrial electrorefining to investigate copper and
nickel electrodeposition reactions. By understanding how metal
electrodeposition works at the molecular level, they hope to place
electrorefining and electroplating on a sound scientific footing..
Another
important aspect of electrometallurgy is metal dissolution, a
process used by the microelectronics industry in printing electronic
circuits. The same process also causes metals to deteriorate during
corrosion. Corrosion protection constitutes one of our most important
economic and technological challenges. Led by Prof. Jacek Lipkowski,
and in collaboration with Ontario Hydro and Atomic Energy of Canada,
centre members have developed a mixture of inhibitors recently
certified for use in Canadian nuclear reactors to protect against
corrosion of coolant circuits. The project is an example of a
successful University-Industry collaboration that developed new
Canadian technology and transferred knowledge from University
to Industry.
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